The ADC VREF is A3V3.
The ADC is 12-bit
The ADC values range from (0) to (4096), and can be estimated int(Vapplied/3v3*4096).
All analog input pin Structures are only 3v3 tolerant.
NEVER exceed 4.0 V on analog input pins. (STM32 DM00037051 Section 5.2)